Synthesis and crystal structure of lutidinium aquafluorooxovanadate(IV)

Autor(en)
Alojz Demsar, Ivan Leban, Gerald Giester
Abstrakt

The complex (LutH)2[V2F6O2(H2O) 2] was prepared from aqueous HF solution of VO2+ and lutidine. The X-ray structure revealed dimeric anions connected to the chain by hydrogen bonds. The effect of the cation and intraionic hydrogen bonds on the stability of the bioctahedral anion is discussed.

Organisation(en)
Institut für Mineralogie und Kristallographie
Externe Organisation(en)
University of Ljubljana
Journal
Acta Chimica Slovenica
Band
49
Seiten
259-265
Anzahl der Seiten
7
ISSN
1318-0207
Publikationsdatum
2002
Peer-reviewed
Ja
ÖFOS 2012
1051 Geologie, Mineralogie
Link zum Portal
https://ucris.univie.ac.at/portal/de/publications/synthesis-and-crystal-structure-of-lutidinium-aquafluorooxovanadateiv(12d72fea-6b45-48bd-a584-f8f755e19c0e).html