Synthesis and crystal structure of lutidinium aquafluorooxovanadate(IV)

Autor(en)

Alojz Demsar, Ivan Leban, Gerald Giester

Abstrakt

The complex (LutH)2[V2F6O2(H2O) 2] was prepared from aqueous HF solution of VO2+ and lutidine. The X-ray structure revealed dimeric anions connected to the chain by hydrogen bonds. The effect of the cation and intraionic hydrogen bonds on the stability of the bioctahedral anion is discussed.

Organisation(en)

Institut für Mineralogie und Kristallographie

Externe Organisation(en)

University of Ljubljana

Journal

Acta Chimica Slovenica

Band

49

Seiten

259-265

Anzahl der Seiten

7

ISSN

1318-0207

Publikationsdatum

2002

Peer-reviewed

Ja

ÖFOS 2012

1051 Geologie, Mineralogie

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/12d72fea-6b45-48bd-a584-f8f755e19c0e