Mixed salt of sarcosine containing dimeric undecafluoridodialuminate anion and fluoride ion
- Autor(en)
- Gerald Giester, V. V. Ghazaryan, Subbiah Thamotharan, María Judith Percino, Aram M. Petrosyan
- Abstrakt
We report on synthesis, structural and vibrational spectroscopic characterization of the (SarH) 6[F5Al- F- AlF5] F (I) salt. The compd. (I) is the first salt of amino acids with a dimeric undecafluoridodialuminate [F5Al- F- AlF5] 5- anion and the first mixed salt of sarcosine with different anions. It crystallizes in orthorhombic system, space group Pbca. The simulated FT- IR spectrum for a cluster which comprises 13 cations, [F5Al- F- AlF5] 5- anion and a fluoride anions built from the crystal structure is compared with the exptl. spectrum and agree reasonably well.
- Organisation(en)
- Institut für Mineralogie und Kristallographie
- Externe Organisation(en)
- Shanmugha Arts, Science, Technology & Research Academy, Benemérita Universidad Autónoma de Puebla, National Academy of Sciences of the Republic of Armenia
- Journal
- Journal of Fluorine Chemistry
- Band
- 209
- Seiten
- 73-78
- Anzahl der Seiten
- 6
- ISSN
- 0022-1139
- DOI
- https://doi.org/10.1016/j.jfluchem.2018.02.011
- Publikationsdatum
- 02-2018
- Peer-reviewed
- Ja
- ÖFOS 2012
- 104015 Organische Chemie, 104026 Spektroskopie, 105113 Kristallographie
- Schlagwörter
- ASJC Scopus Sachgebiete
- Biochemistry, Inorganic Chemistry, Physical and Theoretical Chemistry, Environmental Chemistry, Organic Chemistry
- Link zum Portal
- https://ucrisportal.univie.ac.at/de/publications/1f220d08-ae99-4a09-b4df-e71d22f3eaa7