Assessing temporal trends and source regions of per- and polyfluoroalkyl substances (PFASs) in air under the Arctic Monitoring and Assessment Programme (AMAP)

Autor(en): Fiona Wong, Mahiba Shoeib, Athanasios Katsoyiannis, Sabine Eckhardt, Andreas Stohl, Pernilla Bohlin-Nizzetto, Henrik Li, Phil Fellin, Yushan Su, Hayley Hung
Abstrakt: Long-term Arctic air monitoring of per- and polyfluoroalkyl substances (PFASs) is essential in assessing their long-range transport and for evaluating the effectiveness of chemical control initiatives. We report for the first time temporal trends of neutral and ionic PFASs in air from three arctic stations: Alert (Canada, 2006–2014); Zeppelin (Svalbard, Norway, 2006–2014) and Andøya (Norway, 2010–2014). The most abundant PFASs were the perfluorooctanoic acid (PFOA), perfluorooctane sulfonic acid (PFOS), perfluorobutanoic acid (PFBA), and fluorotelomer alcohols (FTOHs). All of these chemicals exhibited increasing trends at Alert with doubling times (t₂) of 3.7 years (y) for PFOA, 2.9 y for PFOS, 2.5 y for PFBA, 5.0 y for 8:2 FTOH and 7.0 y for 10:2 FTOH. In contrast, declining or non-changing trends, were observed for PFOA and PFOS at Zeppelin (PFOA, half-life, t_1/2 = 7.2 y; PFOS t_1/2 = 67 y), and Andøya (PFOA t_1/2 = 1.9 y; PFOS t_1/2 = 11 y). The differences in air concentrations and in time trends between the three sites may reflect the differences in regional regulations and source regions. We investigate the source region for particle associated compounds using the Lagrangian particle dispersion model FLEXPART. Model results showed that PFOA and PFOS are impacted by air masses originating from the ocean or land. For instance, PFOA at Alert and PFOS at Zeppelin were dominated by oceanic air masses whereas, PFOS at Alert and PFOA at Zeppelin were influenced by air masses transported from land.
Organisation(en): Institut für Meteorologie und Geophysik
Externe Organisation(en): Environment and Climate Change Canada, Norwegian Institute for Air Research, AirZone One Ltd.
Journal: Atmospheric Environment
Band: 172
Seiten: 65-73
Anzahl der Seiten: 9
ISSN: 1352-2310
DOI: https://doi.org/10.1016/j.atmosenv.2017.10.028
Publikationsdatum: 01-2018
Peer-reviewed: Ja
ÖFOS 2012: 105206 Meteorologie
Schlagwörter
ASJC Scopus Sachgebiete: Allgemeine Umweltwissenschaft, Atmospheric Science
Link zum Portal: https://ucrisportal.univie.ac.at/de/publications/25570817-1c3e-43b8-9482-93c87e4c6c58

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