On the ternary Laves phases Ti(Mn1-xAlx)2 with MgZn2-type
- Autor(en)
- Xinlin Yan, Xingqiu Chen, Andrij Grytsiv, Peter Franz Rogl, Raimund Podloucky, Harald Schmidt, Gerald Giester, Xue yong Ding
- Abstrakt
Alloys with composition Ti(Mn1-xAlx)2 (xAl = 0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.55, 0.6, and 0.67) were studied by X-ray powder diffraction (XPD), optical microscopy, electron probe microanalysis (EPMA) and electronic density functional theory. EPMA and XPD defined an extensive solid solution of up to xAl = 0.64 at 900 °C. Structure determination from Rietveld refinements of X-ray powder diffraction data for Ti(Mn1-xAlx)2 (0 ? xAl ? 0.60) and from single crystal X-ray counter data for xAl = 0.2 revealed a C14-MgZn2-type Laves phase, where Ti atoms fully occupy the 4f sites, whereas Mn and Al atoms share the 6h and 2a sites in various ratios. By means of density functional theory, the structural stabilities and site preferences of nine ternary compositions, Ti(Mn1-xAlx)2 (xAl = 0, 0.125, 0.25, 0.375, 0.500, 0.625, 0.750, 0.875, 1.00), were further calculated for a large number of structural models. The derived Al content dependent structural stabilities, lattice parameters, and site occupations as well as enthalpies of formations are in nice agreement with experimental results. Based on the calculated data, we analyzed the occupation behaviour of Al atoms substituting for Mn atoms at the 2a and 6h sites: up to concentrations xAl <0.375 Al atoms prefer the 6h sites, whereas for 0.375 <xAl <0.625 Al atoms prefer the 2a sites. The calculations furthermore revealed that the Al atoms at the 6h sites exhibit a trend of getting paired. © 2007 Elsevier Ltd. All rights reserved.
- Organisation(en)
- Institut für Physikalische Chemie, Institut für Mineralogie und Kristallographie
- Externe Organisation(en)
- Universität Nordostchinas
- Journal
- Intermetallics
- Band
- 16
- Seiten
- 16-26
- Anzahl der Seiten
- 11
- ISSN
- 0966-9795
- DOI
- https://doi.org/10.1016/j.intermet.2007.07.005
- Publikationsdatum
- 2008
- Peer-reviewed
- Ja
- ÖFOS 2012
- 104017 Physikalische Chemie, 105113 Kristallographie, 104011 Materialchemie
- Link zum Portal
- https://ucrisportal.univie.ac.at/de/publications/35f7c0c2-12ce-4158-bf1a-c6db8480b641