Polyethylene microplastics influence the transport of organic contaminants in soil

Autor(en)
Thorsten Hüffer, Florian Metzelder, Gabriel Sigmund, Sophie Slawek, Torsten C. Schmidt, Thilo Hofmann
Abstrakt

Plastics are now found in all natural environments including soil. The effects of microplastics in terrestrial systems, however, remain largely unexplored. Polyethylene is one of themass-manufactured polymers found in terrestrial environments. It is used in many different sectors, for example in agricultural mulches, composite materials, and packaging. The presence of microplastics in soil, including polyethylene, can affect the transport of hydrophobic organic pollutants including pesticides. The objective of this study was to investigate the influence of polyethylene microplastics (b250 μm) on the transport of two selected organic plant-protection agents
(atrazine and 4-(2,4-dichlorophenoxy) butyric acid) in soil under different aqueous conditions, using inverse liquid chromatography. The distribution coefficients for the sorbates that were sorbed to pure polyethylene microplastic were found to be significantly smaller than those for the sorbates sorbed to pure soil. The addition
of 10% (w/w) polyethylene to the soil therefore led to an overall reduction in sorption, but the sorption trends due to variations in pH and ionic strength were not affected. The results imply that the presence of polyethylene microplastics in soilmay therefore increase the mobility of organic contaminants by reducing the sorption capacity
of natural soils, which must be validated by further research.

Organisation(en)
Forschungsplattform Plastics in the Environment and Society
Externe Organisation(en)
Universität Duisburg-Essen, Deutsches Textilforschungszentrum Nord-West GmbH, Technische Universität München, IWW Zentrum Wasser, Universität Wien
Journal
Science of the Total Environment
Band
657
Seiten
242-247
Anzahl der Seiten
6
ISSN
0048-9697
DOI
https://doi.org/10.1016/j.scitotenv.2018.12.047
Publikationsdatum
12-2018
Peer-reviewed
Ja
ÖFOS 2012
105906 Umweltgeowissenschaften
Schlagwörter
ASJC Scopus Sachgebiete
Pollution, Waste Management and Disposal, Environmental engineering, Environmental Chemistry
Link zum Portal
https://ucrisportal.univie.ac.at/de/publications/4824e1e3-541d-4e3f-844c-7b88d46d2c88