Superconductivity in novel Ge-based skutterudites: {Sr,Ba}Pt4Ge12

Autor(en)
Gerald Giester, Andrij Grytsiv, Nataliya Melnychenko-Koblyuk, Raimund Podloucky, Peter Franz Rogl, Xingqiu Chen, Ernst Bauer, Gerfried Hilscher, Esmaeil Royanian, Herwig Michor, H Kaldarar
Abstrakt

Combining expts. and ab initio models we report on SrPt4Ge12 and BaPt4Ge12 as members of a novel class of superconducting skutterudites, where Sr or Ba atoms stabilize a framework entirely formed by Ge-atoms. Below Tc = 5.35 K, and 5.10 K for BaPt4Ge12 and SrPt4Ge12, resp., electron-phonon coupled supercond. emerges, ascribed to intrinsic features of the Pt-Ge framework, where Ge-p states dominate the electronic structure at the Fermi energy.

Organisation(en)
Institut für Mineralogie und Kristallographie, Institut für Physikalische Chemie
Externe Organisation(en)
Arizona State University, Technische Universität Wien
Journal
Physical Review Letters
Band
99
ISSN
0031-9007
Publikationsdatum
2007
Peer-reviewed
Ja
ÖFOS 2012
105113 Kristallographie, 103033 Supraleitung, 105116 Mineralogie
Link zum Portal
https://ucrisportal.univie.ac.at/de/publications/49e601db-f75d-4b55-8e07-5a1c9f5de55e