New chemical analogs of triglycine sulfate

Autor(en)
V. V. Ghazaryan, Michel Fleck, A.M. Petrosyan
Abstrakt

Triglycine sulfate (TGS) and its analogs can be presented by the mol. structure AH(A···AH)?Y, where A is an amino acid (glycine in TGS) in zwitter-?ionic form, AH is a protonated cationic amino acid, (A···AH) is a dimeric cation, where A and AH are connected by a short hydrogen bond, and Y is a divalent anion. Doing research on amino acid hexafluorosilicates we obtained a series of salts with different compns., including four hexafluorosilicate salts which chem. are analogs of triglycine sulfate. Those are GlyH(Gly···GlyH)?SiF6 (I)?, SarH(Sar···SarH)?SiF6·2H2O (II)?, L-?AlaH(L-?Ala···L-?AlaH)?SiF6·H2O (III) and L-?ProH(L-?Pro···L-?ProH)?SiF6·H2O (IV)?. We have already published our results on crystals (II) and (III)?. In this work we report our results on the crystals (I) and (IV)?.

Organisation(en)
Institut für Mineralogie und Kristallographie
Externe Organisation(en)
National Academy of Sciences of the Republic of Armenia
Journal
Journal of Crystal Growth
Band
401
Seiten
857-862
Anzahl der Seiten
6
ISSN
0022-0248
DOI
https://doi.org/10.1016/j.jcrysgro.2013.11.054
Publikationsdatum
11-2013
Peer-reviewed
Ja
ÖFOS 2012
104015 Organische Chemie, 104017 Physikalische Chemie, 105113 Kristallographie
Schlagwörter
ASJC Scopus Sachgebiete
Condensed Matter Physics, Materials Chemistry, Inorganic Chemistry
Link zum Portal
https://ucrisportal.univie.ac.at/de/publications/49fca345-5efe-46e7-a7d6-4a7cafcf297c