The new mineral baumstarkite and a structural reinvestigation of aramayoite and miargyrite
- Autor(en)
- Herta Silvia Effenberger, Hermann Werner Paar, Daniel M Topa, Alan J Criddle, Michel Fleck
- Abstrakt
Baumstarkite is a new mineral found coating miargyrite from the San Genaro mine, Huancavelica Department, Peru. It is triclinic and the third naturally occurring modification of AgSbS2 besides monoclinic miargyrite and cubic cuboargyrite. The composition is usually close to the ideal formula. However, some grains of baumstarkite show zoned lamellae with As contents up to 11.5 wt% and accords to Ag3(Sb,As)2SbS6. Baumstarkite is isotypic with aramayoite [end-member composition Ag3Sb2BiS6; solid solutions require the extended formula Ag3Sb2(Bi,Sb)S6]. Single-crystal X-ray structure investigations were performed for baumstarkite [type locality, a = 7.766(2), b = 8.322(2), c = 8.814(2) A°, a = 100.62(2), ß = 104.03(2), ? = 90.22(2)°, Z = 2{Ag3Sb3S6}, space group P1¯, R1 (F) = 0.057, wR2(F2) = 0.128], aramayoite [Armonia mine, El Quevar, Argentinia: a = 7.813(2), b = 8.268(2), c = 8.880(2) A°, a = 100.32(2), ß = 104.07(2), ? = 90.18(2)°. Z = 2Ag3Sb2S6, space group P1¯, R1(F) = 0.034, wR2(F2) = 0.084], and miargyrite associated with baumstarkite type material [a = 12.862(3), b = 4.409(1), c = 13.218(3) A°, ß = 98.48(2)°, Z = 8 AgSbS2, space group C2/c, R1 (F) = 0.031, wR2(F2) = 0.082]. The space-group symmetries of aramayoite and miargyrite were revised, and the refinements unambiguously showed that the three investigated minerals are centrosymmetric. In baumstarkite and aramayoite each three atomic sites are occupied by Ag and M = As, Sb, Bi, respectively. The Ag atoms have two short bonded ligands (Ag-S is 2.51 to 2.58 A°). The M1 and M2 sites are [3 + 3] coordinated and are predominantly occupied by (Sb, As) atoms (M-S = 2.44 to 2.54 A° and > 3.09 A°). The [2 + 2 + 2] coordination of the M3 atom differs in the two mineral species: the two shortest bond lengths in baumstarkite are smaller (2.51 A°) than in aramayoite (2.64 A°) to allow for the different sizes of the Sb and Bi atoms, respectively; the medium bond lengths are similar (2.75 to 2.82 A°) and the longest bond lengths are >3.02 A°. Considering only the nearest-neighbor environments, baumstarkite and aramayoite feature zigzag chains parallel to 1010], which are linked together to form layers parallel to (001). In miargyrite [2 + 2] and [2] coordinated Ag atoms are linked by SbS3 pyramids to form a three-dimensional network.
- Organisation(en)
- Institut für Mineralogie und Kristallographie
- Externe Organisation(en)
- Paris-Lodron Universität Salzburg, Natural History Museum London
- Journal
- American Mineralogist: an international journal of earth and planetary materials
- Band
- 87
- Seiten
- 753-764
- Anzahl der Seiten
- 12
- ISSN
- 0003-004X
- Publikationsdatum
- 2002
- Peer-reviewed
- Ja
- ÖFOS 2012
- 1051 Geologie, Mineralogie
- Link zum Portal
- https://ucrisportal.univie.ac.at/de/publications/5b973356-81b5-4972-9e26-0d566d10cea1