L-Tryptophan L-tryptophanium chloride

Autor(en)
V. V. Ghazaryan, Michel Fleck, Aram M. Petrosyan
Abstrakt

L-Tryptophan L-tryptophanium chloride is a new salt with (A···A+) type dimeric cation. It crystallizes in the monoclinic system (space group P21, Z = 2). The asym. unit contains one zwitterionic L-tryptophan mol., one L-tryptophanium cation and one chloride anion. The dimeric cation is formed by a O-H···O hydrogen bond with the O···O distance equal to 2.5556(18) Å. The IR and Raman spectra of the crystal are studied and compared with the spectra of L-tryptophanium chloride.

Organisation(en)
Institut für Mineralogie und Kristallographie
Externe Organisation(en)
National Academy of Sciences of the Republic of Armenia
Journal
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Band
136
Seiten
743-750
Anzahl der Seiten
8
ISSN
1386-1425
DOI
https://doi.org/10.1016/j.saa.2014.09.090
Publikationsdatum
09-2014
Peer-reviewed
Ja
ÖFOS 2012
104015 Organische Chemie, 104011 Materialchemie, 105113 Kristallographie
Schlagwörter
ASJC Scopus Sachgebiete
Analytical Chemistry, Instrumentation, Atomic and Molecular Physics, and Optics, Spectroscopy
Link zum Portal
https://ucrisportal.univie.ac.at/de/publications/ltryptophan-ltryptophanium-chloride(6774ad06-1cd8-42cf-aac7-c471fc68cf63).html