a-Cs2Cr3O10

Autor(en)
Uwe Kolitsch
Abstrakt

The title compound, dicaesium trichromium(VI) oxide, is the orthorhombic (space group Pbca) modification of Cs2Cr3O10. The compound is isotypic with its NH4 and Rb trichromate analogues. The structure contains discrete [Cr3O10]2- anions [Cr - O - Cr = 136.58 (11) and 140.30 (12)°] linked via two non-equivalent irregularly 11-coordinated Cs+ cations [d av(Cs - O) = 3.224 and 3.272 A°]. All atoms are in general positions. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

Organisation(en)
Institut für Mineralogie und Kristallographie
Journal
Acta Crystallographica. Section E: Structure Reports Online
Band
59
ISSN
1600-5368
DOI
https://doi.org/10.1107/S1600536803026473
Publikationsdatum
2003
Peer-reviewed
Ja
ÖFOS 2012
1051 Geologie, Mineralogie
Link zum Portal
https://ucrisportal.univie.ac.at/de/publications/74d95712-94af-4658-a077-a90265f2bdd6