Synthesis and structural peculiarities of gallium complexes with novel paullone derivatives

Autor(en)

Werner Ginzinger, Vladimir Arion, Gerald Giester, Mathea Sophia Galanski, Bernhard Keppler

Abstrakt

9-Bromo-7,12-dihydroindolo[3,2-d][1]benzazepin-6-ylhydrazine was reacted with 2-acetylpyridine to give a Schiff base as a potential tridentate ligand. The reaction of this ligand with gallium chloride afforded complexes of 1:1 and 2:1 stoichiometry. The results of X-ray diffraction studies of the ligand and both gallium complexes are reported and compared with the data for a related gallium complex with a Schiff base obtained from 9-bromo-7,12-dihydroindolo[3,2-d][1]benzazepin-6-ylhydrazine and 2-hydroxybenzaldehyde.

Organisation(en)

Institut für Anorganische Chemie, Institut für Mineralogie und Kristallographie

Journal

Central European Journal of Chemistry

Band

6

Seiten

340-346

Anzahl der Seiten

7

ISSN

1895-1066

Publikationsdatum

2008

Peer-reviewed

Ja

ÖFOS 2012

104003 Anorganische Chemie, 105113 Kristallographie

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/78ef4c28-c199-4983-9c0e-bc3db20c1713