Crystal structure at 296 and 150 K, vibrational spectra and thermal behaviour of sarcosine sarcosinium nitrate

Autor(en)

Michel Fleck, V. V. Ghazaryan, A.M. Petrosyan

Abstrakt

Crystals of sarcosine sarcosinium nitrate(2 Sar HNO3) have been grown and characterized at 296and 150 K by single crystal XRD and vibrational spectroscopy.The species was found to be triclinic (space groupP11, a ¼ 5.320(1)A° , b ¼ 6.578(1)A° , c ¼ 15.957(2)A° ,a ¼ 95.448(6), b ¼ 95.944(6), g ¼ 93.410(6), V ¼551.6(1)A° 3, and Z ¼ 2 at 296 K), with a dimeric sarcosine sarcosinium cation and a nitrate anion in the asymmetricunit. A very strong hydrogen bond connects the moleculeswithin the dimer. In addition, the tensor of thermalexpansion was determined for the temperature range of 200to 290 K. A strong anisotropy was detected, with thermalexpansion along the c-axis approximately 14 times as strongas along the a-axis.

Organisation(en)

Institut für Mineralogie und Kristallographie

Externe Organisation(en)

National Academy of Sciences of the Republic of Armenia

Journal

Zeitschrift für Kristallographie - Crystalline Materials

Band

227

Seiten

819-824

Anzahl der Seiten

6

ISSN

2194-4946

Publikationsdatum

2012

Peer-reviewed

Ja

ÖFOS 2012

105113 Kristallographie, 1030 Physik, Astronomie, 104015 Organische Chemie

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/7b0c41bb-5ec1-4d73-bb9c-3a2a275376aa