Zn1.86Cd0.14(OH)VO4

Autor(en)
Tamara Đorđević, J. Stojanovic, Ljiljana Karanovic
Abstrakt

The title compound, dizinc cadmium hydroxide tetraoxidovanadate,Zn1.86Cd0.14(OH)VO4, was prepared under lowtemperaturehydrothermal conditions. It is isostructural withZn2(OH)VO4 and Cu2(OH)VO4. In the crystal structure,chains of edge-sharing [ZnO6] octahedra are interconnectedby VO4 tetrahedra (site symmetries of both Vatoms and theircoordination polyhedra are .m.) to form a three-dimensional[Zn(OH)VO4]2_framework with channels occupied by Znand Zn/Cd cations adopting trigonal-bipyramidal anddistorted octahedral coordinations, respectively. Zn1.86-Cd0.14(OH)VO4 is topologically related to adamite-typephases, and descloizite- and tsumcorite-type structures.

Organisation(en)
Institut für Mineralogie und Kristallographie
Externe Organisation(en)
University of Belgrade
Journal
Acta Crystallographica. Section E: Structure Reports Online
Band
66
Anzahl der Seiten
1
ISSN
1600-5368
DOI
https://doi.org/10.1107/S1600536810044806
Publikationsdatum
2010
Peer-reviewed
Ja
ÖFOS 2012
105113 Kristallographie
Link zum Portal
https://ucrisportal.univie.ac.at/de/publications/84d5ff69-d461-4a85-a3b3-0f47cae98757