(NH4)4Cd(HSeIVO3) 2(SeVIO4)2: A new structure type with krošhnkite-like chains

Autor(en)
Uwe Kolitsch
Abstrakt

The triclinic structure of tetrammonium cadmium dihydrogenselenite(IV) diselenate(VI), (NH4)4Cd(HSeIVO 3)2 (SeVIO4)2 was discussed. The compound had kro?hnkite-like heteropolyhedral chains in which CdO6 octahedra were linked via bridging HSeO3 groups. The charge-balancing NH4 groups were involved in weak hydrogen bonding, whereas the H atom of the HSeO3 group provided a strong hydrogen bond. The unit-cell parameter determination of the compound indicated no change in symmetry upon cooling.

Organisation(en)
Institut für Mineralogie und Kristallographie
Journal
Acta Crystallographica. Section C: Crystal Structure Communications
Band
60
ISSN
0108-2701
Publikationsdatum
2004
Peer-reviewed
Ja
ÖFOS 2012
1051 Geologie, Mineralogie
Link zum Portal
https://ucrisportal.univie.ac.at/de/publications/9f802576-ba8c-429f-bcd6-f081904a730c