RbFe(HAsO₄)₂ and TlFe(HAsO₄)₂, two new hydrogenarsenates adopting two closely related structure types

Autor(en)

Karolina Schwendtner, Uwe Kolitsch

Abstrakt

Rubidium iron bis[hydrogen arsenate(V)], RbFe(HAsO4)2, and thallium iron bis[hydrogen arsenate(V)], TlFe(HAsO4)2, were grown under mild hydrothermal conditions (T = 493 K, 7 d). RbFe(HAsO4)2 adopts the RbFe(HPO4)2 structure type (space group R3c), while TlFe(HAsO4)2 crystallizes in the (NH4)Fe(HPO4)2 structure type (space group P1). Both compounds have tetrahedral-octahedral framework topologies. The M+ cations are located in channels of the respective framework and are disordered in TlFe(HAsO4)2, which may suggest that the M+ cations can move in the channels.

Organisation(en)

Institut für Mineralogie und Kristallographie

Externe Organisation(en)

Technische Universität Wien, Naturhistorisches Museum Wien (NHM)

Journal

Acta Crystallographica. Section E: Crystallographic Communications

Band

E74

Seiten

766-771

Anzahl der Seiten

6

ISSN

1600-5368

DOI

https://doi.org/10.1107/S2056989018006473

Publikationsdatum

05-2018

Peer-reviewed

Ja

ÖFOS 2012

104003 Anorganische Chemie, 104011 Materialchemie, 105113 Kristallographie

Schlagwörter

ASJC Scopus Sachgebiete

Condensed Matter Physics, Allgemeine Chemie, Allgemeine Materialwissenschaften

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/a8dd3dc4-5de0-422b-967e-0c9f9231b6ea