Crystal structure of the tetragonal polymorph of bis(1-ethyl-3-methylimidazolium) tetrabromidocadmate

Autor(en)

Tamara Đorđević, Sabrina Stefanie Gerger, Ljiljana Karanovic

Abstrakt

Both unique Cd atoms in the tetragonal polymorph of bis(1-ethyl-3-methylimidazolium)tetrabromidocadmate, (C6H11N2)2[CdBr4], occupy special positions(site symmetry 4). The crystal structure consists of isolated tetrahedral[CdBr4]2 anions which are surrounded by 1-ethyl-3-methylimidazolium cations.The methyl and ethyl side chains of the cations show positional disorder in a0.590 (11):0.410 (11) ratio. In the crystal, (C6H11N2)+ cations display three weakC-H...Br hydrogen-bond interactions through the imidazolium ring H atomswith the Br ligands of the surrounding complex anions. The alkyl groups of theside chains are not involved in hydrogen bonding.

Organisation(en)

Institut für Mineralogie und Kristallographie

Externe Organisation(en)

University of Belgrade

Journal

Acta Crystallographica. Section E: Crystallographic Communications

Band

E72

Seiten

1013-1016

Anzahl der Seiten

4

DOI

https://doi.org/10.1107/S2056989016009919

Publikationsdatum

07-2016

Peer-reviewed

Ja

ÖFOS 2012

104015 Organische Chemie, 104011 Materialchemie, 105113 Kristallographie

Schlagwörter

ASJC Scopus Sachgebiete

Condensed Matter Physics, Allgemeine Chemie, Allgemeine Materialwissenschaften

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/a9f83c4c-c216-488b-b708-d9a4e8aa4682