Analysis of engineered nanomaterials in complex matrices (environment and biota): General considerations and conceptual case studies

Autor(en)
Frank von der Kammer, Jason Unrine, Armand Masion, Stephen Klaine
Abstrakt

Advances in the study of the environmental fate, transport, and ecotoxicological effects of engineered nanomaterials (ENMs) have been hampered by a lack of adequate techniques for the detection and quantification of ENMs at environmentally relevant concentrations in complex media. Analysis of ENMs differs from traditional chemical analysis because both chemical and physical forms must be considered. Because ENMs are present as colloidal systems, their physicochemical properties are dependent on their surroundings. Therefore, the simple act of trying to isolate, observe, and quantify ENMs may change their physicochemical properties, making analysis extremely susceptible to artifacts. Many analytical techniques applied in materials science and other chemical/biological/physical disciplines may be applied to ENM analysis as well; however, environmental and biological studies may require that methods be adapted to work at low concentrations in complex matrices. The most pressing research needs are the development of techniques for extraction, cleanup, separation, and sample storage that introduce minimal artifacts to increase the speed, sensitivity, and specificity of analytical techniques, as well as the development of techniques that can differentiate between abundant, naturally occurring particles, and manufactured nanoparticles. Environ. Toxicol. Chem. 2012;31:3249. (C) 2011 SETAC

Organisation(en)
Externe Organisation(en)
University of Kentucky, CEREGE - Centre Européen de Recherche et d'Enseignement des Géosciences de l'Environnement, Clemson University
Journal
Environmental Toxicology and Chemistry
Band
31
Seiten
32-49
Anzahl der Seiten
18
ISSN
0730-7268
DOI
https://doi.org/10.1002/etc.723
Publikationsdatum
2012
Peer-reviewed
Ja
ÖFOS 2012
105904 Umweltforschung
Link zum Portal
https://ucrisportal.univie.ac.at/de/publications/ac9c8af1-6cf1-4b53-8815-1f1759f0c846