Structural and thermal characterization of Fe(III) and Fe(II) complexes with tridentate ono pyridoxal semicarbazone

Autor(en)

Gerald Giester

Abstrakt

Mol. and crystal structure of diaqua-sulphato(pyridoxal semicarbazone-ONO)iron(II) and dichloroaqua(pyridoxal semicarbazone-ONO)iron(III) complexes with tridentate ONO pyridoxal semicarbazone ligand, PLSC, of formula [FeII(PLSC)(H2O)2SO4] and [FeIII(PLSC)(H2O)Cl2]Cl is reported. Thermal decompn. of the compds. was followed in argon and air gas carriers. The deaquation mechanism is discussed in the view of the crystal structure, emphasizing the complexity of the related parameters and processes.

Organisation(en)

Institut für Mineralogie und Kristallographie

Journal

Journal of Thermal Analysis and Calorimetry: an international forum for thermal studies

Band

90

Seiten

549-555

Anzahl der Seiten

7

ISSN

1388-6150

Publikationsdatum

2007

Peer-reviewed

Ja

ÖFOS 2012

105113 Kristallographie

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/af338aff-12a3-43d8-9d81-eb075733beb1