Hexakis (propargyl-1H-tetrazole) Iron(II) X₂ [X = BF₄,ClO₄]-spin switchable complexes with functionalization potential and the myth of the explosive SCO compound

Autor(en)

Marco Seifried, Christian Knoll, Gerald Giester, Michael Reissner, Danny Müller, Peter Weinberger

Abstrakt

Spin crossover complexes with ligands suitable for further functionalization could allow for an easy access to multifunctional switchable materials. Within this context, we recently characterized the Fe(II) SCO complexes of propargyl-1H-tetrazole. Although the design of the ligand seems similar to the one of the well-known propyl-1H-tetrazole, the spin transition behavior is notably different. Both compounds reported herein feature a gradual spin transition with a T-1/2 shifted to lower temperatures, compared to the more flexible propyl-ligand. Due to the potential instable structure of these compounds, especially of the perchlorate complex, we also investigated our compounds with regard to their sensitivity against thermal and mechanical stress. These experiments led to the conclusion that the proper handling includes no enhanced risk of explosive decomposition.

Organisation(en)

Institut für Mineralogie und Kristallographie

Externe Organisation(en)

Technische Universität Wien

Journal

Magnetochemistry

Band

2

Anzahl der Seiten

13

ISSN

2312-7481

DOI

https://doi.org/10.3390/magnetochemistry2010012

Publikationsdatum

02-2016

Peer-reviewed

Ja

ÖFOS 2012

104011 Materialchemie, 105113 Kristallographie

Schlagwörter

ASJC Scopus Sachgebiete

Electronic, Optical and Magnetic Materials, Chemistry (miscellaneous), Materials Chemistry

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/hexakis-propargyl1htetrazole-ironii-x2-x--bf4clo4spin-switchable-complexes-with-functionalization-potential-and-the-myth-of-the-explosive-sco-compound(b5e72c86-fcd3-4506-921e-735acdda43cd).html