Growth and characterization of <i>L</i>-prolinium phosphite

Autor(en)

M. Fleck, V. V. Ghazaryan, Aram M. Petrosyan

Abstrakt

Single crystal of L-prolinium phosphite was grown by evaporation method from aqueous solution. Itcrystallizes in the orthorhombic system (space group P212121, Z = 4). The asymmetric unit contains oneL-prolinium cation and one phosphite (HPO2(OH)) anion. The phosphite anions form a chain by hydrogenbond OAH. . .O with O. . .O distance 2.5601(15) Å parallel [010]. The L-prolinium cations bridge twochains of anions by OAH. . .O and NAH. . .O hydrogen bonds with O. . .O and N. . .O distances 2.505(2) Åand 2.718(2) Å respectively. The infrared and Raman spectra are registered and discussed. Thermalbehavior was studied. Phase-matched SHG was observed.

Organisation(en)

Institut für Mineralogie und Kristallographie

Externe Organisation(en)

National Academy of Sciences of the Republic of Armenia

Journal

Journal of Molecular Structure

Band

1079

Seiten

460-464

Anzahl der Seiten

5

ISSN

0022-2860

DOI

https://doi.org/10.1016/j.molstruc.2014.09.051

Publikationsdatum

09-2014

Peer-reviewed

Ja

ÖFOS 2012

105113 Kristallographie, 104011 Materialchemie, 104015 Organische Chemie

Schlagwörter

ASJC Scopus Sachgebiete

Spectroscopy, Analytical Chemistry, Inorganic Chemistry, Organic Chemistry

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/growth-and-characterization-of-lprolinium-phosphite(d37374fe-99df-4a0f-bfaf-1b145db63589).html