KCr<sub>3</sub>(SO<sub>4</sub>)<sub>2</sub>(OH)<sub>6</sub>

Autor(en)
C. L. Lengauer, G. Giester, E. Irran
Abstrakt

The new compound, KCr3(SO4)2(OH)6, was prepared by low-hydrothermal synthesis. The structure was refined by the Rietveld technique in space group R3m (Z = 3), a =7.2416(3) Å, c = 17.0788(9) Å, V = 775.63 Å3, Rp = 7.7, Rwp =10.1, RB = 6.8. The compound is isotypic with alunite, KAl3(SO4)2(OH)6. The temperature of decomposition under nitrogen atmosphere to a hitherto unknown form is about 550 K. The water content of alunite-type compounds is discussed.

Organisation(en)
Institut für Mineralogie und Kristallographie
Externe Organisation(en)
Universität Wien
Journal
Powder Diffraction
Band
9
Seiten
265-271
Anzahl der Seiten
7
ISSN
0885-7156
Publikationsdatum
12-1994
Peer-reviewed
Ja
ÖFOS 2012
105116 Mineralogie, 105113 Kristallographie
ASJC Scopus Sachgebiete
Radiation, Allgemeine Materialwissenschaften, Instrumentation, Condensed Matter Physics
Link zum Portal
https://ucrisportal.univie.ac.at/de/publications/d7ec5ebb-557b-4902-8275-bceb41cb532e