Two three-dimensional coordination polymers of lead(II) with iminodiacetate and naphthalene-dicarboxylate anions: Synthesis, characterization and luminescence behavior
- Autor(en)
- Debdoot Hazari, Swapan Kumar Jana, Michel Fleck, Ennio Zangrando, Sudipta Dalai
- Abstrakt
Two lead(II) compounds [Pb3(idiac)3(phen)2(H2O)]·2(H2O) (1) and [Pb(ndc)]n (2), where H2idiac=iminodiacetic acid, phen=1,10-phenanthroline and H2ndc=naphthalene-2,6-dicarboxylic acid, have been synthesized and structurally characterized. Single crystal X-ray diffraction analysis showed that compound 1 is a discrete trinuclear complex (of two-fold symmetry) which evolves to a supramolecular 3D network via π–π interactions, while in compound 2 the naphthalene dicarboxylate anion act as a linker to form a three dimensional architecture, where the anion adopts a bis-(bidentate bridging) coordination mode connecting four Pb(II) centers. The photoluminescence property of the two complexes has been studied.
- Organisation(en)
- Institut für Mineralogie und Kristallographie
- Externe Organisation(en)
- Vidyasagar University, Università degli Studi di Trieste
- Journal
- Journal of Solid State Chemistry
- Band
- 219
- Seiten
- 43-48
- Anzahl der Seiten
- 6
- ISSN
- 0022-4596
- DOI
- https://doi.org/10.1016/j.jssc.2014.07.004
- Publikationsdatum
- 07-2014
- Peer-reviewed
- Ja
- ÖFOS 2012
- 104015 Organische Chemie, 104021 Strukturchemie, 105113 Kristallographie
- Schlagwörter
- ASJC Scopus Sachgebiete
- Electronic, Optical and Magnetic Materials, Condensed Matter Physics, Ceramics and Composites, Materials Chemistry, Inorganic Chemistry, Physical and Theoretical Chemistry
- Link zum Portal
- https://ucrisportal.univie.ac.at/de/publications/dcbd0f6f-4521-44e4-a46c-3926963a0703