Superposition model analysis from polarized electronic absorption spectra of Co2+ in trigonally distorted octahedra in brucite-type Co(OH)2
- Autor(en)
- Michael Andrut, Manfred Wildner
- Abstrakt
Temperature dependent polarized spectra and effective applicability of the superposition model (SM) concept to d-block element compounds were analyzed. The magnitude of the `correct' SM parameters of Co2+ for future application to structurally and/or chemically less defined systems was also discussed. It was observed that the specific position of closely related ligands within the spectrochemical series affects the intrinsic parameters.
- Organisation(en)
- Institut für Mineralogie und Kristallographie
- Externe Organisation(en)
- Universität Wien
- Journal
- Journal of Physics: Condensed Matter
- Band
- 13
- Seiten
- 7353-7361
- Anzahl der Seiten
- 9
- ISSN
- 0953-8984
- DOI
- https://doi.org/10.1088/0953-8984/13/33/315
- Publikationsdatum
- 2001
- Peer-reviewed
- Ja
- ÖFOS 2012
- 1051 Geologie, Mineralogie
- Link zum Portal
- https://ucrisportal.univie.ac.at/de/publications/e4b90c60-c31f-4553-8eea-97a2c033e675