Thiocyanates of nickel and caesium: Cs2NiAg2(SCN) 6·2H2O and CsNi(SCN)3
- Autor(en)
- Michel Fleck
- Abstrakt
The crystal structures of dicaesium nickel disilver hexathiocyanate dihydrate, Cs2NiAg2(SCN)6.2H2O, (I), and caesium nickel trithiocyanate. CsNi(SCN)3, (II), have been determined by single-crystal X-ray diffraction at 273 K. Compounds (I) and (II) are monoclinic, with P21/c and P21/n symmetry, respectively. In (I), the Ni atom lies on an inversion centre; in (II), there are two independent Ni atoms, each of which lies on an inversion centre. The coordination polyhedra and the bonding schemes in the structures are discussed.
- Organisation(en)
- Institut für Mineralogie und Kristallographie
- Journal
- Acta Crystallographica. Section C: Crystal Structure Communications
- Band
- 60
- ISSN
- 0108-2701
- DOI
- https://doi.org/10.1107/S0108270104008790
- Publikationsdatum
- 2004
- Peer-reviewed
- Ja
- ÖFOS 2012
- 1051 Geologie, Mineralogie
- Link zum Portal
- https://ucrisportal.univie.ac.at/de/publications/efe72714-0611-40df-ac95-01cf738700ca