Major and trace element geochemistry of superficial sediments and suspended particulate matter of shallow saline lakes in Eastern Austria

Autor(en)
Anja Stojanovic, Daniel Kogelnig, Barbara Mitteregger, Dieter Mader, Franz Jirsa, Rudolf Krachler, Regina Krachler
Abstrakt

General geochemical parameters of water, superficial sediments, and suspended particulate matter (SPM) were determined from small shallow saline lakes (soda ponds) as well as from lake Neusiedlersee in eastern Austria. Additionally, instrumental neutron activation analysis (INAA) was used to determine the distribution of major, rare earth and other trace elements in superficial sediments and SPM. Chemical results show remarkable differences in salinity and ionic strength between the investigated ponds. Anthropogenic effects, such as drawdown of ground water level and a loss of lake water due to drainage, are clearly reflected in obtained chemical and geological data. Due to a strong dependence of the complexation and scavenging behavior of the rare earth elements (REE) on ionic strength, a significant difference between REE concentrations in soda ponds with different anthropogenic impact was found. The content and composition of authigenic evaporitic minerals in superficial sediments and SPM clearly differ with a fluctuating water level and salt concentration. Furthermore, we determined the distribution of major and trace elements in superficial sediments of a nearby fluvial system. Our results show a clear correlation between REE superficial sediment concentrations in anthropogenically degraded soda ponds and fluvial system. Therefore, we assume that REE concentrations of sediments and SPM are suitable for the study of geochemical changes of inland saline lakes due to anthropogenic impacts on water balance.

Organisation(en)
Institut für Anorganische Chemie, Department für Lithosphärenforschung
Journal
Chemie der Erde / Geochemistry
Band
69
Seiten
223-234
Anzahl der Seiten
12
ISSN
0009-2819
DOI
https://doi.org/10.1016/j.chemer.2009.03.001
Publikationsdatum
2009
Peer-reviewed
Ja
ÖFOS 2012
104003 Anorganische Chemie, 105105 Geochemie
Link zum Portal
https://ucrisportal.univie.ac.at/de/publications/98613591-34fc-46dc-9327-44ad97ac844a