Refinement of the layered titanosilicate AM-1 from single-crystal X-ray diffraction data
- Author(s)
- Ekkehart Tillmanns, Christian Lengauer, Uwe Kolitsch
- Abstract
The structure of the layered noncentrosymmetric titanosilicate AM-1 (also known as JDF-L1, disodium titanium tetrasilicate dihydrate), Na4Ti2Si8O22·4H2O, grown as small single crystals without the use of organics, has been refined from single-crystal X-ray diffraction data. The H atom has been located for the first time, and the hydrogen-bonding scheme is also characterized by IR and Raman spectroscopy. All atoms are in general positions except for the Na, the Ti, one Ti-bound O, one Si-bound O and the water O atoms (site symmetries 2, 4, 4, 2 and 2, respectively).
- Organisation(s)
- Department of Mineralogy and Crystallography
- Journal
- Acta Crystallographica. Section E: Structure Reports Online
- Volume
- E63
- No. of pages
- 186
- ISSN
- 1600-5368
- Publication date
- 2007
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 105113 Crystallography
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/067361c3-2584-444b-b294-a4346203aab6