Distinguishing volcanic from impact glasses—The case of the Cali glass (Colombia)

Author(s)
Ludovic Ferrière, Alvaro P. Crósta, Wencke Wegner, Eugen Libowitzky, Fabio Iwashita, Christian Köberl
Abstract

Natural glass occurs on Earth in different geological contexts, mainly as volcanic glass, fulgurites, and impact glass. All these different types of glasses are predominantly composed of silica with variable amounts of impurities, especially the alkalis, and differ in their water content due to their mode of formation. Distinguishing between different types of glasses, on Earth and also on the Moon and on other planetary bodies, can be challenging. This is particularly true for glasses of impact and volcanic origin. Because glass is often used for the determination of the age of geological events, even if out of geological context, as well as to derive pressure and temperature constraints, or to evaluate the volatile contents of magmas and their source regions, we rely on methods that can unambiguously distinguish between the different types of glasses. We used the case of the Cali glass, found in an extended area close to the city of Cali in western Colombia, which was previously suggested to be of impact or volcanic origin, to show that, using a multimethod approach (i.e., combining macroscopic observations, chemical and isotopic data, and H2O content), it is possible to distinguish between different formation modes. A suite of Cali glass samples was analyzed using electron microprobe, instrumental neutron activation analysis, thermal ionization mass spectrometry, and Fourier-transform infrared spectroscopy, allowing us to definitively exclude an impact origin and instead classify these glasses as a rhyolitic volcanic glass (obsidian). Our results suggest that other “unusual glass occurrences” that are claimed, but not convincingly proven, to be of impact origin should be reexamined using the same methodology as that applied here.

Organisation(s)
Department of Lithospheric Research, Department of Mineralogy and Crystallography
External organisation(s)
Naturhistorisches Museum Wien (NHM), Universidad de Los Andes (Colombia), Universidade Estadual de Campinas
Journal
Geology
Volume
49
Pages
1421–1425
No. of pages
5
ISSN
0091-7613
DOI
https://doi.org/10.1130/G48925.1
Publication date
07-2021
Peer reviewed
Yes
Austrian Fields of Science 2012
105116 Mineralogy, 105101 General geology
Keywords
ASJC Scopus subject areas
Geology
Portal url
https://ucrisportal.univie.ac.at/en/publications/11ae419d-752a-4c22-979b-78556778693b