Synthesis and crystal structure of lutidinium aquafluorooxovanadate(IV)

Author(s)
Alojz Demsar, Ivan Leban, Gerald Giester
Abstract

The complex (LutH)2[V2F6O2(H2O) 2] was prepared from aqueous HF solution of VO2+ and lutidine. The X-ray structure revealed dimeric anions connected to the chain by hydrogen bonds. The effect of the cation and intraionic hydrogen bonds on the stability of the bioctahedral anion is discussed.

Organisation(s)
Department of Mineralogy and Crystallography
External organisation(s)
University of Ljubljana
Journal
Acta Chimica Slovenica
Volume
49
Pages
259-265
No. of pages
7
ISSN
1318-0207
Publication date
2002
Peer reviewed
Yes
Austrian Fields of Science 2012
1051 Geology, Mineralogy
Portal url
https://ucrisportal.univie.ac.at/en/publications/12d72fea-6b45-48bd-a584-f8f755e19c0e