Mixed salt of sarcosine containing dimeric undecafluoridodialuminate anion and fluoride ion
- Author(s)
- Gerald Giester, V. V. Ghazaryan, Subbiah Thamotharan, María Judith Percino, Aram M. Petrosyan
- Abstract
We report on synthesis, structural and vibrational spectroscopic characterization of the (SarH) 6[F5Al- F- AlF5] F (I) salt. The compd. (I) is the first salt of amino acids with a dimeric undecafluoridodialuminate [F5Al- F- AlF5] 5- anion and the first mixed salt of sarcosine with different anions. It crystallizes in orthorhombic system, space group Pbca. The simulated FT- IR spectrum for a cluster which comprises 13 cations, [F5Al- F- AlF5] 5- anion and a fluoride anions built from the crystal structure is compared with the exptl. spectrum and agree reasonably well.
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- Shanmugha Arts, Science, Technology & Research Academy, Benemérita Universidad Autónoma de Puebla, National Academy of Sciences of the Republic of Armenia
- Journal
- Journal of Fluorine Chemistry
- Volume
- 209
- Pages
- 73-78
- No. of pages
- 6
- ISSN
- 0022-1139
- DOI
- https://doi.org/10.1016/j.jfluchem.2018.02.011
- Publication date
- 02-2018
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 104015 Organic chemistry, 104026 Spectroscopy, 105113 Crystallography
- Keywords
- ASJC Scopus subject areas
- Biochemistry, Inorganic Chemistry, Physical and Theoretical Chemistry, Environmental Chemistry, Organic Chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/1f220d08-ae99-4a09-b4df-e71d22f3eaa7