Simultaneous manipulation of iron(ii) spin crossover and LIESST behaviour using pressure, temperature and light
- Author(s)
- Gabriela Handzlik, Kamil F. Dziubek, Michael Hanfland, Dawid Pinkowicz
- Abstract
Spin crossover (SCO) and light-induced excited spin state trapping (LIESST) effects were studied using high pressure X-ray diffraction at cryogenic temperatures on a single crystal of the {[FeII(pyrazole)4]2[NbIV(CN)8]·4H2O}n (FeNb) coordination polymer. The studied compound does not show SCO or LIESST at ambient pressure, but these effects can be enforced by a mechanical stimulus. The obtained results demonstrate the manipulation of the spin state via the appropriate combination of multiple stimuli simultaneously.
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- Jagiellonian University in Krakow, European Synchrotron Radiation Facility ESRF
- Journal
- Dalton Transactions
- Volume
- 53
- Pages
- 7677-7681
- No. of pages
- 5
- ISSN
- 1477-9226
- DOI
- https://doi.org/10.1039/d4dt00509k
- Publication date
- 04-2024
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 105113 Crystallography, 104003 Inorganic chemistry, 104017 Physical chemistry, 104011 Materials chemistry
- Keywords
- ASJC Scopus subject areas
- Inorganic Chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/2891da47-5a2e-4c11-a654-6ad8d9895ab8