Uranium extraction from aqueous solutions by ionic liquids

Author(s)
Michaela Srncik, Daniel Kogelnig, Anja Stojanovic, Wilfried Körner, Regina Krachler, Gabriele Wallner
Abstract

For determining natural levels of 236U with its environmental abundance of 10-16% rather large sample volumes (?30 L) are necessary, therefore the conventional radiochemical uranium analysis (pre-concentration and column chromatography) is very time consuming. To speed up the procedure hydrophobic ionic liquids (ILs) were evaluated as a potential extraction agent for uranium from aqueous solutions. High selectivity and efficiency for uranium compared to calcium and magnesium in natural water was achieved with tricaprylmethylammonium thiosalicylate, [A336][TS]. Uranium was stripped successfully from the investigated ILs with 2 M HNO3.

Organisation(s)
Department of Inorganic Chemistry
Journal
Applied Radiation and Isotopes
Volume
67
Pages
2146-2149
No. of pages
4
ISSN
0969-8043
DOI
https://doi.org/10.1016/j.apradiso.2009.04.011
Publication date
2009
Peer reviewed
Yes
Austrian Fields of Science 2012
104003 Inorganic chemistry
Portal url
https://ucrisportal.univie.ac.at/en/publications/2ee1cbe1-b6b7-4f9b-b932-cba5ae95b7a0