Superconductivity and spin fluctuations in Th,U Pt4Ge12 skutterudites

Author(s)
Ernst Bauer, Xingqiu Chen, Peter Franz Rogl, Gerfried Hilscher, Herwig Michor, Esmaeil Royanian, Raimund Podloucky, Gerald Giester, Oksana Sologub, Antonio P. Goncalves
Abstract

Merging exptl. data and ab initio calcns., we report on ThPt4Ge12 and UPt4Ge12 as further members of germanium-based skutterudites. For ThPt4Ge12 electron-phonon coupled supercond. develops below Tc=4.75 K, ascribed to intrinsic features of the Pt-Ge framework where Ge-p states dominate the electronic structure at the Fermi energy. Ruderman-Kittel-Kasuya-Yosida coupling via the Ge framework is too weak to enable magnetic ordering in nonsuperconducting UPt4Ge12.

Organisation(s)
Department of Physical Chemistry, Department of Mineralogy and Crystallography
External organisation(s)
Technische Universität Wien, Instituto Superior Técnico, Nuclear and Technological Institute (ITN)
Journal
Physical Review B
Volume
78
Pages
1-6
No. of pages
6
ISSN
1098-0121
Publication date
2008
Peer reviewed
Yes
Austrian Fields of Science 2012
105113 Crystallography, 1040 Chemistry
Portal url
https://ucrisportal.univie.ac.at/en/publications/490295af-f862-4223-a7e2-c4f01c233990