Superconductivity in novel Ge-based skutterudites: {Sr,Ba}Pt4Ge12

Author(s)
Gerald Giester, Andrij Grytsiv, Nataliya Melnychenko-Koblyuk, Raimund Podloucky, Peter Franz Rogl, Xingqiu Chen, Ernst Bauer, Gerfried Hilscher, Esmaeil Royanian, Herwig Michor, H Kaldarar
Abstract

Combining expts. and ab initio models we report on SrPt4Ge12 and BaPt4Ge12 as members of a novel class of superconducting skutterudites, where Sr or Ba atoms stabilize a framework entirely formed by Ge-atoms. Below Tc = 5.35 K, and 5.10 K for BaPt4Ge12 and SrPt4Ge12, resp., electron-phonon coupled supercond. emerges, ascribed to intrinsic features of the Pt-Ge framework, where Ge-p states dominate the electronic structure at the Fermi energy.

Organisation(s)
Department of Mineralogy and Crystallography, Department of Physical Chemistry
External organisation(s)
Arizona State University, Technische Universität Wien
Journal
Physical Review Letters
Volume
99
ISSN
0031-9007
Publication date
2007
Peer reviewed
Yes
Austrian Fields of Science 2012
105113 Crystallography, 103033 Superconductivity, 105116 Mineralogy
Portal url
https://ucrisportal.univie.ac.at/en/publications/49e601db-f75d-4b55-8e07-5a1c9f5de55e