Thermal behavior and structural transformation in the chabazite-type zeolite willhendersonite, KCaAl₃ Si₃O₁₂·5H₂O

Author(s)

R. X. Fischer, V. Kahlenberg, C. L. Lengauer, E. Tillmanns

Abstract

Single crystals of the chabazite-type zeolite mineral willhendersonite, KCaAl₃ Si₃O₁₂. 5H₂O (from Bellerberg, eastern Eifel district, Germany), were studied by X-ray diffraction methods between 100 and 500 K. The zeolite shows a phase transition from triclinic to rhombohedral symmetry between 350 and 375 K under dry nitrogen and between 450 and 475 K under humid air. Under these conditions, the unit-cell parameters change from P1̄ at 350 K [a, b, c (Å); α, β, γ(°); V(Å ³) = 9.210, 9.210, 9.405; 92.75, 92.80, 90.80; 795.8) to R3̄ at 375 K (a = 9.380 Å, α = 91.40°, V = 824.5 ų), and from P1̄ at 450 K [a, b, c (Å); α, β, γ (°); V (ų) = 9.215, 9.215, 9.415; 92.65, 92.85, 90.75; 797.5] to R3̄ at 475 K (a = 9.375 Å, α = 91.35°, V = 823.8 ų), respectively. The crystal structures were refined based on X-ray diffraction data collected at room temperature [P1̄; a, b, c (Å); α, β, γ (°); V (ų) = 9.248(5), 9.259(5), 9.533(5); 92.313(5), 92.761(5), 89.981(5); 814.7(8)], at 373 K [P1̄; a, b, c (Å); α, β, γ (°); V (ų,) = 9.205(5), 9.231(5), 9.442(5); 92.550(5), 93.086(5), 90.519(5); 800.3(8)], and at 423 K [R3̄, a = 9.411(4) Å, α = 91.48(1)°, V= 832.7(6) ų]. Upon heating, the elliptical 8-rings of willhendersonite expand to a triangular shape in the rhombohedral structure with upper and lower rings in the double 6-ring (D6R) twisted by 60° to each other corresponding to the center of symmetry in the center of the D6R. The changes in the framework are accompanied by migration of cations, partly assuming unfavorably low coordinations in the high temperature structure due to the loss of H₂O molecules. Rehydration at room temperature yields the triclinic structure of willhendersonite, although the single crystals become polysynthetically twinned.

Organisation(s)

Department of Mineralogy and Crystallography

External organisation(s)

Jacobs Universität Bremen, Leopold-Franzens-Universität Innsbruck, University of Vienna

Journal

American Mineralogist

Volume

93

Pages

1317-1325

No. of pages

9

ISSN

0003-004X

Publication date

2008

Peer reviewed

Yes

Austrian Fields of Science 2012

105116 Mineralogy, 105113 Crystallography

Keywords

ASJC Scopus subject areas

Geophysics, Geochemistry and Petrology

Portal url

https://ucrisportal.univie.ac.at/en/publications/4aa49003-e301-4f6c-8e81-4d194f1abdfa