Geochemistry of a confirmed Precambrian impact ejecta deposit

Author(s)
Matthew Stephen Huber, Christian Koeberl, Frank C. Smith, Billy P. Glass, Roland Mundil, Iain McDonald
Abstract

Samples from a single outcrop of the Graenseso spherule layer, Midternaes, South Greenland, consist of a spherule-bearing dolomixtite with matrix-supported intraclasts up to 1 m in size. In addition to field observations, we performed mineralogical and whole rock geochemical analysis, including electron microprobe, neutron activation analysis, X-ray fluorescence, and mass spectrometry of the horizon and the overlying and underlying strata. We show that the spherules are petrographically similar to those in the Zaonega spherule layer, Karelia, Russia. Our petrographic and chemical results are consistent with the previous suggestion that the Grænsesø layer correlates with the Zaonega layer, and it is possible that both layers are related to the Vredefort impact event. The samples containing spherules, as well as the overlying rocks, have elevated REEs compared to the underlying pre-impact layer, suggestive of a new continental source of sediment that may be coincident with the impact event. Zircons separated from the lower part of the Grænsesø spherule layer display complex age patterns suggesting that they have genetically different origins based on distinctly different Th/U ratios. Crystallization ages of all groups are ≥ 2.8 Ga, with ~2.8 Ga representing a time of major crustal growth globally. Therefore, we cannot conclusively determine in this study if the zircons are locally derived or if they are transported with the ejecta. The spherule layer was deposited by a high-energy, subaqueous debris flow, an origin that is consistent with the hypothesis that the layer was deposited by impact-induced waves and/or currents.

Organisation(s)
Department of Lithospheric Research
External organisation(s)
University of Delaware, Berkeley Geochronology Center, Cardiff University, University of the Free State, University of Vienna, Naturhistorisches Museum Wien (NHM)
Journal
Meteoritics and Planetary Science
Volume
54
Pages
2254-2272
No. of pages
19
ISSN
1086-9379
DOI
https://doi.org/10.1111/maps.13271
Publication date
2019
Peer reviewed
Yes
Austrian Fields of Science 2012
105105 Geochemistry
Keywords
ASJC Scopus subject areas
Geophysics, Space and Planetary Science
Portal url
https://ucrisportal.univie.ac.at/en/publications/5a979f08-51d4-49e2-b7cc-1a4f1ac62aa7