a-Cs2Cr3O10

Author(s)
Uwe Kolitsch
Abstract

The title compound, dicaesium trichromium(VI) oxide, is the orthorhombic (space group Pbca) modification of Cs2Cr3O10. The compound is isotypic with its NH4 and Rb trichromate analogues. The structure contains discrete [Cr3O10]2- anions [Cr - O - Cr = 136.58 (11) and 140.30 (12)°] linked via two non-equivalent irregularly 11-coordinated Cs+ cations [d av(Cs - O) = 3.224 and 3.272 A°]. All atoms are in general positions. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

Organisation(s)
Department of Mineralogy and Crystallography
Journal
Acta Crystallographica. Section E: Structure Reports Online
Volume
59
ISSN
1600-5368
DOI
https://doi.org/10.1107/S1600536803026473
Publication date
2003
Peer reviewed
Yes
Austrian Fields of Science 2012
1051 Geology, Mineralogy
Portal url
https://ucrisportal.univie.ac.at/en/publications/74d95712-94af-4658-a077-a90265f2bdd6