Synthesis and structural peculiarities of gallium complexes with novel paullone derivatives

Author(s)
Werner Ginzinger, Vladimir Arion, Gerald Giester, Mathea Sophia Galanski, Bernhard Keppler
Abstract

9-Bromo-7,12-dihydroindolo[3,2-d][1]benzazepin-6-ylhydrazine was reacted with 2-acetylpyridine to give a Schiff base as a potential tridentate ligand. The reaction of this ligand with gallium chloride afforded complexes of 1:1 and 2:1 stoichiometry. The results of X-ray diffraction studies of the ligand and both gallium complexes are reported and compared with the data for a related gallium complex with a Schiff base obtained from 9-bromo-7,12-dihydroindolo[3,2-d][1]benzazepin-6-ylhydrazine and 2-hydroxybenzaldehyde.

Organisation(s)
Department of Inorganic Chemistry, Department of Mineralogy and Crystallography
Journal
Central European Journal of Chemistry
Volume
6
Pages
340-346
No. of pages
7
ISSN
1895-1066
Publication date
2008
Peer reviewed
Yes
Austrian Fields of Science 2012
104003 Inorganic chemistry, 105113 Crystallography
Portal url
https://ucrisportal.univie.ac.at/en/publications/78ef4c28-c199-4983-9c0e-bc3db20c1713