Zn1.86Cd0.14(OH)VO4
- Author(s)
- Tamara Đorđević, J. Stojanovic, Ljiljana Karanovic
- Abstract
The title compound, dizinc cadmium hydroxide tetraoxidovanadate,Zn1.86Cd0.14(OH)VO4, was prepared under lowtemperaturehydrothermal conditions. It is isostructural withZn2(OH)VO4 and Cu2(OH)VO4. In the crystal structure,chains of edge-sharing [ZnO6] octahedra are interconnectedby VO4 tetrahedra (site symmetries of both Vatoms and theircoordination polyhedra are .m.) to form a three-dimensional[Zn(OH)VO4]2_framework with channels occupied by Znand Zn/Cd cations adopting trigonal-bipyramidal anddistorted octahedral coordinations, respectively. Zn1.86-Cd0.14(OH)VO4 is topologically related to adamite-typephases, and descloizite- and tsumcorite-type structures.
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- University of Belgrade
- Journal
- Acta Crystallographica. Section E: Structure Reports Online
- Volume
- 66
- No. of pages
- 1
- ISSN
- 1600-5368
- DOI
- https://doi.org/10.1107/S1600536810044806
- Publication date
- 2010
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 105113 Crystallography
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/84d5ff69-d461-4a85-a3b3-0f47cae98757