Structural and thermal characterization of Fe(III) and Fe(II) complexes with tridentate ono pyridoxal semicarbazone
- Author(s)
- Gerald Giester
- Abstract
Mol. and crystal structure of diaqua-sulphato(pyridoxal semicarbazone-ONO)iron(II) and dichloroaqua(pyridoxal semicarbazone-ONO)iron(III) complexes with tridentate ONO pyridoxal semicarbazone ligand, PLSC, of formula [FeII(PLSC)(H2O)2SO4] and [FeIII(PLSC)(H2O)Cl2]Cl is reported. Thermal decompn. of the compds. was followed in argon and air gas carriers. The deaquation mechanism is discussed in the view of the crystal structure, emphasizing the complexity of the related parameters and processes.
- Organisation(s)
- Department of Mineralogy and Crystallography
- Journal
- Journal of Thermal Analysis and Calorimetry: an international forum for thermal studies
- Volume
- 90
- Pages
- 549-555
- No. of pages
- 7
- ISSN
- 1388-6150
- Publication date
- 2007
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 105113 Crystallography
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/af338aff-12a3-43d8-9d81-eb075733beb1