Bis(tetramethylammonium) hexa-aquadodeca-μ-bromo-octahedrohexatantalum tetrabromide dihydrate

Author(s)
Marija Vojnovic, Drazan Jozic, Gerald Giester, Berislav Peric, Pavica Planinic, Nevenka Brnicevic
Abstract

The novel title compound, [(CH3)4N]2[Ta6Br12(H2O)6]Br4·-2H2O, with a [Ta6Br12]2+ cluster unit, has been prepared and structurally characterized. The compound crystallizes in space group C2/c, with a twofold axis passing through the cluster and the centre of symmetry located between the clusters. The nearest neighbouring cluster units are aligned along the crystallographic c axis, forming a one-dimensional chain pattern.

Organisation(s)
Department of Mineralogy and Crystallography
External organisation(s)
Rudjer Boskovic Institute
Journal
Acta Crystallographica. Section C: Crystal Structure Communications
Volume
58
ISSN
0108-2701
DOI
https://doi.org/10.1107/S0108270102001841
Publication date
2002
Peer reviewed
Yes
Austrian Fields of Science 2012
1051 Geology, Mineralogy
Portal url
https://ucrisportal.univie.ac.at/en/publications/b1c811ac-fdbd-4c49-9b04-fb74670ea8a5