Mineralogical and Chemical Characterization of Roman Slag from the Archaeological Site of Castra (Ajdovščina, Slovenia)

Author(s)
Sabina Kramar, V. Tratnik, I. M. Hrovatin, Ana Mladenovic, Helmut Pristacz, Nastja Rogan-Smuc
Abstract

This study deals with the mineralogical and chemical characterization of archaeometallurgical material from the Roman archaeological site of Castra (Ajdovščina, western Slovenia). Samples were initially analysed via optical microscopy and X-ray powder diffraction, with the composition of individual phases then determined using scanning electron microscopy coupled with electron-dispersive spectroscopy, and Raman microspectroscopy. Chemical investigation was carried out by using inductively coupled plasma atomic emission spectroscopy to measure the major element content. The results showed that the slag originated from iron smithing operations, with calcium-rich olivines, as well as wuestite and leucite, the most abundant phases. The investigated slags were also found to be characterized by significantly high lime levels, which probably promoted the formation of the calcium-rich olivines.

Organisation(s)
Department of Mineralogy and Crystallography
External organisation(s)
Institute for the Protection of Cultural Heritage of Slovenia, University of Ljubljana, Slovenian National Building and Civil Engineering Institute, Independent researcher
Journal
Archaeometry
Volume
57
Pages
704-719
No. of pages
16
ISSN
0003-813X
DOI
https://doi.org/10.1111/arcm.12116
Publication date
06-2015
Peer reviewed
Yes
Austrian Fields of Science 2012
105116 Mineralogy, 104001 General chemistry, 107001 Archaeometry
Keywords
ASJC Scopus subject areas
History, Archaeology
Portal url
https://ucrisportal.univie.ac.at/en/publications/mineralogical-and-chemical-characterization-of-roman-slag-from-the-archaeological-site-of-castra-ajdovina-slovenia(b2af887a-0fb9-4838-aedf-f8d931d10ca9).html