Two new zincophosphates, (H3NCH2CH2NH3)2[Zn(µ-PO4)2] and (NH4)[(H3N)Zn{(µ-PO4)Zn}3]: Crystal structures and relationships to similar open framework zinco- and aluminophospates
- Author(s)
- Ljiljana Karanovic, Dejan Poleti, Tamara Đorđević, Sabina Sutovic
- Abstract
Two new zincophosphates, bis(ethylenediammonim) catena-bis(µ-phosphato)zincate, (H3NCH2CH2NH3)2[Zn(µ-PO4)2] (1), and ammonium ammine-tris(µ-phosphato)tetrazincate, (NH4)[(H3N)Zn{(µ-PO4)Zn}3] (2), were synthesized under hydrothermal conditions and their crystal structures were determined by single-crystal X-ray diffraction analysis. The crystal structure of 1 consists of infinite macroanionic ZnP2O84- chains, running along the [0 0 1] direction, and diprotonated ethylenediammonium cations, H2en2+. The crystal structure of 2 is built up from ZnO4, Zn(NH3)O3 and PO4 vertex-sharing tetrahedra connected to form an open 3D framework. The ammonium groups, NH4+, are located in the channels formed by 8M-rings extending along [1 0 0]. In order to study vibrational behavior of H2en2+ and NH4+ cations, NH3 molecules in 1 and 2, single-crystal Raman spectra were obtained. Structural, chemical and topological similarities to the other open framework zinco- and aluminophosphates incorporating different guest species are discussed.
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- University of Belgrade
- Journal
- Journal of Solid State Chemistry
- Volume
- 184
- Pages
- 2506-2515
- No. of pages
- 10
- ISSN
- 0022-4596
- Publication date
- 2011
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 105113 Crystallography
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/b7cd65ae-460e-4aab-aaa7-0a0ad1c26f5b