On the influence of non-LTE effects on OH rotational temperatures

Author(s)
Stefan Noll, Wolfgang Kausch, Stefan Kimeswenger, Stefanie Unterguggenberger, Amy M. Jones
Abstract

OH airglow is an important tracer of the state of the mesopause and its variability at about 87 km, since it is the dominating emission from the upper atmosphere in the optical to near-infrared wavelength regime. A great deal of the world-wide mesopause temperature records are based on OH. Lines of single OH bands are used to derive rotational temperatures, which are expected to be close to the ambient temperature if only lines from the lowest rotational levels are considered. However, establishing a rotational-translational equilibrium requires a sufficient frequency of suitable collisions, since the nascent level population distribution of OH by the hydrogen-ozone reaction is dominated by high rotational levels and radiative transitions can change the level by one quantum at most. At least for the upper parts of the OH emission layer, it is not clear whether this criterion is fulfilled, since the concentration of the crucial quencher O2 is relatively low.

Organisation(s)
Department of Astrophysics
External organisation(s)
Leopold-Franzens-Universität Innsbruck
Journal
Geophysical Research Abstracts
Volume
17
ISSN
1029-7006
Publication date
03-2015
Peer reviewed
Yes
Austrian Fields of Science 2012
103003 Astronomy, 103004 Astrophysics
Portal url
https://ucrisportal.univie.ac.at/en/publications/on-the-influence-of-nonlte-effects-on-oh-rotational-temperatures(c4480d77-19f8-48e3-981b-34a6d445278a).html