CoSO<sub>4</sub>·H<sub>2</sub>O and its continuous transition compared to the compression properties of isostructural kieserite-type polymorphs
- Author(s)
- Manfred Wildner, Martin Ende, Johannes M. Meusburger, Roland Kunit, Philipp Matzinger, Dominik Talla, Ronald Miletich
- Abstract
The kieserite-type compound cobalt(II) sulfate monohydrate, CoSO4·H2O, has been investigated under isothermal (T = 295 K) hydrostatic compression up to 10.1 GPa in a diamond anvil cell by means of single-crystal X-ray diffraction and Raman spectroscopy. The monoclinic α-phase (space group C2/c) undergoes a second-order ferroelastic phase transition at Pc = 2.40(3) GPa to a triclinic β-phase (space group P11). Lattice elasticities derived from fitting third-order Birch-Murnaghan equations of state to the pressure dependent unit-cell volume data yield V0 = 354.20(6) Å3, K0 = 53.0(1.7) GPa, K′ = 5.7(1.8) for the α-phase and V0 = 355.9(8) Å3, K0 = 45.2(2.6) GPa, K′ = 6.6(6) for the β-phase. Crystal structure data of the high-pressure polymorph were determined at 2.98(6) and 4.88(6) GPa. The most obvious structural feature and thus a possible driving mechanism of the phase transition, is a partial rearrangement in the hydrogen bonding system. However, a comparative analysis of pressure-induced changes in the four kieserite-type compounds investigated to date suggests that the loss of the point symmetry 2 at the otherwise rather rigid SO4 tetrahedron, allowing symmetrically unrestricted tetrahedral rotations and edge tiltings in the β-phase, could be the actual driving mechanism of the phase transition.
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- University of Exeter, University of Vienna
- Journal
- Zeitschrift fur Kristallographie - Crystalline Materials
- Volume
- 236
- Pages
- 225–237
- No. of pages
- 13
- ISSN
- 2194-4946
- DOI
- https://doi.org/10.1515/zkri-2021-2038
- Publication date
- 09-2021
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 105116 Mineralogy, 105113 Crystallography
- Keywords
- ASJC Scopus subject areas
- Condensed Matter Physics, General Materials Science, Inorganic Chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/c4c384fa-ca13-4bc3-a314-585218fd7a0e