Diiodo(3,4,5,6-tetrahydropyrimidinium-2-thiolato-S)mercury(II)
- Author(s)
- Dubravka Matkovic-Calogovic, Zora Popovic, Gordana Pavlovic, Zeljka Soldin, Gerald Giester
- Abstract
The reaction of 3,4,5,6-tetrahydropyrimidine-2-thione (H4pymtH) with mercury(II) iodide in methanol in a 1:1 molar ratio resulted in the formation of single crystals of the title compound, [Hg(C4H8N2S)I2]. The Hg atom is coordinated by one S atom from H4pymtH at 2.456 (2) A° and by two I atoms at distances of 2.6872 (7) and 2.7044 (6) A°, and has a characteristic deformed trigonal coordination geometry. The molecule has crystallographic m symmetry but the Hg atom is disordered above and below the mirror plane.
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- University of Zagreb
- Journal
- Acta Crystallographica. Section C: Crystal Structure Communications
- Volume
- 57
- Pages
- 409-411
- No. of pages
- 3
- ISSN
- 0108-2701
- DOI
- https://doi.org/10.1107/S0108270101001822
- Publication date
- 2001
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 1051 Geology, Mineralogy
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/d31b77a4-f0f2-403e-8b3a-691fcb2e261a