Synthesis of ferrocenylglucose phosphonite and bisphosphinite: Pd(II) and Pt(II) complexes, Pd-catalyzed allylic alkylation
- Author(s)
- Alexey Nazarov, Christian Hartinger, Vladimir Arion, Gerald Giester, Bernhard Keppler
- Abstract
The synthesis and characterization of the new phosphorus containing ligands and the corresponding Pd(II) and Pt(II) complexes are reported. The molecular structure of 4,6-bis-O-(diphenylphosphino)-2,3-(ferrocene-1,1'-dicarbonyl)-O- methyl-a-D-glucopyranoside was determined by X-ray diffraction methods. The new ligands show good activity (90%) and moderate stereoselectivity (39% ee) in the Pd-catalyzed enantioselective allylic alkylation. Π2002 Elsevier Science Ltd. All rights reserved.
- Organisation(s)
- Department of Inorganic Chemistry, Department of Mineralogy and Crystallography
- Journal
- Tetrahedron
- Volume
- 58
- Pages
- 8489-8492
- No. of pages
- 4
- ISSN
- 0040-4020
- Publication date
- 2002
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 1051 Geology, Mineralogy
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/d326cd17-e339-46a4-ad7f-e9522afd5f08