Growth and characterization of <i>L</i>-prolinium phosphite
- Author(s)
- M. Fleck, V. V. Ghazaryan, Aram M. Petrosyan
- Abstract
Single crystal of L-prolinium phosphite was grown by evaporation method from aqueous solution. It crystallizes in the orthorhombic system (space group P212121, Z = 4). The asymmetric unit contains one L-prolinium cation and one phosphite (HPO2(OH))- anion. The phosphite anions form a chain by hydrogen bond OH...O with O...O distance 2.5601(15) Å parallel [0 1 0]. The L-prolinium cations bridge two chains of anions by OH...O and NH...O hydrogen bonds with O...O and N...O distances 2.505(2) Å and 2.718(2) Å respectively. The infrared and Raman spectra are registered and discussed. Thermal behavior was studied. Phase-matched SHG was observed.
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- National Academy of Sciences of the Republic of Armenia
- Journal
- Journal of Molecular Structure
- Volume
- 1079
- Pages
- 460-464
- No. of pages
- 5
- ISSN
- 0022-2860
- DOI
- https://doi.org/10.1016/j.molstruc.2014.09.051
- Publication date
- 09-2014
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 105113 Crystallography, 104011 Materials chemistry, 104015 Organic chemistry
- Keywords
- ASJC Scopus subject areas
- Spectroscopy, Analytical Chemistry, Inorganic Chemistry, Organic Chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/growth-and-characterization-of-lprolinium-phosphite(d37374fe-99df-4a0f-bfaf-1b145db63589).html