Structural diversity in manganese(II) complexes with multidentate N-donor imino pyridyl ligands
- Author(s)
- Asad Masoumi, Masoumeh Servati Gargari, Ghodrat Mahmoudi, Barbara Machura, Vincent Lynch, Gerald Giester, Marjan Abedi, Paul Hazendonk
- Abstract
Four Mn(NCS)2 based compounds of the types [Mn(SCN)2(L1)]·EtOH (1), [Mn(SCN)2(L2)]·½EtOH (2), [Mn(SCN)2(L3)] (3), and [Mn(SCN)2(L4)2]n·3nMeCN (4) [L1 = benzilbis((pyridin-2-yl)methylidenehydrazone), L2 = benzilbis((acetylpyridin-2-yl)methylidenehydrazone, L3 = benzilbis((phenylpyridin-2-yl)methylidenehydrazone, and L4 = benzilbis((pyridin-3-yl)methylidenehydrazone)] were synthesized and characterized by single-crystal X-ray diffraction studies, elemental analysis, and IR spectroscopy. The first three complexes of general formula Mn(SCN)2(L1-3) consist of discrete units, whereas the fourth one consists of one-dimensional coordination polymer. The central metal atoms in 1-4 exhibit a distorted octahedral arrangement.
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- Islamic Azad University , University of Silesia in Katowice, University of Texas, Austin, University of Lethbridge
- Journal
- Zeitschrift für Anorganische und Allgemeine Chemie
- Volume
- 641
- Pages
- 1176-1181
- No. of pages
- 6
- ISSN
- 0044-2313
- DOI
- https://doi.org/10.1002/zaac.201400560
- Publication date
- 03-2015
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 104015 Organic chemistry, 104004 Chemical biology, 104011 Materials chemistry, 105113 Crystallography
- Keywords
- ASJC Scopus subject areas
- Inorganic Chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/structural-diversity-in-manganeseii-complexes-with-multidentate-ndonor-imino-pyridyl-ligands(d6844259-7248-4c29-8923-b81f3786b35f).html