Two three-dimensional coordination polymers of lead(II) with iminodiacetate and naphthalene-dicarboxylate anions: Synthesis, characterization and luminescence behavior
- Author(s)
- Debdoot Hazari, Swapan Kumar Jana, Michel Fleck, Ennio Zangrando, Sudipta Dalai
- Abstract
Two lead(II) compounds [Pb3(idiac)3(phen)2(H2O)]·2(H2O) (1) and [Pb(ndc)]n (2), where H2idiac=iminodiacetic acid, phen=1,10-phenanthroline and H2ndc=naphthalene-2,6-dicarboxylic acid, have been synthesized and structurally characterized. Single crystal X-ray diffraction analysis showed that compound 1 is a discrete trinuclear complex (of two-fold symmetry) which evolves to a supramolecular 3D network via π–π interactions, while in compound 2 the naphthalene dicarboxylate anion act as a linker to form a three dimensional architecture, where the anion adopts a bis-(bidentate bridging) coordination mode connecting four Pb(II) centers. The photoluminescence property of the two complexes has been studied.
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- Vidyasagar University, Università degli Studi di Trieste
- Journal
- Journal of Solid State Chemistry
- Volume
- 219
- Pages
- 43-48
- No. of pages
- 6
- ISSN
- 0022-4596
- DOI
- https://doi.org/10.1016/j.jssc.2014.07.004
- Publication date
- 07-2014
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 104015 Organic chemistry, 104021 Structural chemistry, 105113 Crystallography
- Keywords
- ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials, Condensed Matter Physics, Ceramics and Composites, Materials Chemistry, Inorganic Chemistry, Physical and Theoretical Chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/dcbd0f6f-4521-44e4-a46c-3926963a0703